Answers to both are linked above and available on our developers website.
1) All information about our implementation of PIV can be found here -
https://developers.yubico.com/PIV/Information about certificate slots is here -
https://developers.yubico.com/PIV/Intro ... slots.html2) PIV / OpenPGP / Yubico Authenticator (YubiOATH applet, if you want to be specific) / U2F / OTP - these are all autonomous
ykneo-oath is the OATH applet on the NEO where the "authenticator app" credentials get stored when using Yubico Authenticator. It is not related to PIV or OpenPGP keys/certificates.