Removing PIV - delete the certificates on the card (or reset the applet) with PIV Manager, then remove the hashes with sc_auth:
viewtopic.php?t=2434&p=9037No, it's not possible to force it right now (I've seen hacks that
kind of work, but so far it has been very inconsistent and all methods end up breaking some functionality in macOS). FileVault, sudo in Terminal, and Security & Privacy section of System Preferences all currently don't support smart cards. Until these issues are cleared up in Sierra, I wouldn't recommend attempting to force a smart card requirement.