$baseParams['__YKVAL_SYNC_CURL_OPTS__'] = array(
        CURLOPT_SSL_VERIFYPEER => false
);

<?php

$urls = array(
   "https://testval2/wsapi/2.0/verify?id=1&nonce=sopxxrlklguqquyvbkwwqthyvofukjzc&otp=llkddjeccccckgvidcnbhhjvbvuicbdjnhblitfhvlfr&timestamp=1",
   "http://testval2/wsapi/2.0/verify?id=1&nonce=sopxxrlklguqquyvbkwwqthyvofukjzd&otp=llkddjeccccckgvidcnbhhjvbvuicbdjnhblitfhvlfr&timestamp=1"
);

$mh = curl_multi_init();

var_dump('start');
foreach ($urls as $i => $url) {
    $conn[$i] = curl_init($url);
    curl_setopt($conn[$i], CURLOPT_RETURNTRANSFER, 1);
//    curl_setopt($conn[$i], CURLOPT_CAPATH, "/etc/ssl/certs/");
//    curl_setopt($conn[$i], CURLOPT_CAINFO, "/etc/ssl/certs/ca-certificates.crt");
    curl_setopt($conn[$i], CURLOPT_CAINFO, "/test/blah.pem");
//    curl_setopt($conn[$i], CURLOPT_SSL_VERIFYPEER, 0);
    curl_multi_add_handle($mh, $conn[$i]);
}

var_dump('doloop');
do {
    $status = curl_multi_exec($mh, $active);
    $info = curl_multi_info_read($mh);
    if (false !== $info) {
        var_dump($info);
    }
} while ($status === CURLM_CALL_MULTI_PERFORM || $active);

var_dump('another loop');
foreach ($urls as $i => $url) {
    $res[$i] = curl_multi_getcontent($conn[$i]);
    curl_close($conn[$i]);
}

var_dump('enddump');
var_dump(curl_multi_info_read($mh));

?>

string(5) "start"
string(6) "doloop"
array(3) {
  ["msg"]=>
  int(1)
  ["result"]=>
  int(60) <--- HERE IS THE CURLE_SSL_CACERT ERROR
  ["handle"]=>
  resource(5) of type (curl)
}
array(3) {
  ["msg"]=>
  int(1)
  ["result"]=>
  int(0)
  ["handle"]=>
  resource(6) of type (curl)
}
string(12) "another loop"
string(7) "enddump"
bool(false)

curl 'https://testval2/wsapi/2.0/verify?id=1&nonce=sopxxrlklguqquyvbkwwqthyvofukjzc&otp=llkddjeccccckgvidcnbhhjvbvuicbdjnhblitfhvlfr&timestamp=1'
curl: (60) server certificate verification failed. CAfile: /etc/ssl/certs/ca-certificates.crt CRLfile: none
More details here: http://curl.haxx.se/docs/sslcerts.html

curl performs SSL certificate verification by default, using a "bundle"
 of Certificate Authority (CA) public keys (CA certs). If the default
 bundle file isn't adequate, you can specify an alternate file
 using the --cacert option.
If this HTTPS server uses a certificate signed by a CA represented in
 the bundle, the certificate verification probably failed due to a
 problem with the certificate (it might be expired, or the name might
 not match the domain name in the URL).
If you'd like to turn off curl's verification of the certificate, use
 the -k (or --insecure) option.

 curl --cacert blah.pem 'https://testval2/wsapi/2.0/verify?id=1&nonce=sopxxrlklguqquyvbkwwqthyvofukjzc&otp=llkddjeccccckgvidcnbhhjvbvuicbdjnhblitfhvlfr&timestamp=1'
h=RoeWTtwokPc0wbIQ17rOqHrGux8=
t=2017-06-29T15:15:08Z0971
otp=llkddjeccccckgvidcnbhhjvbvuicbdjnhblitfhvlfr
nonce=sopxxrlklguqquyvbkwwqthyvofukjzc
status=REPLAYED_OTP